Removal of Cd2+ from aqueous solution by zeolite synthesized from Egyptian kaolin


  • Asmaa Kamel Bahgaat Soil Chemistry Dept. Desert Research Center (DRC), Cairo, Egypt https://orcid.org/0000-0002-3697-3109
  • Helmy El-Sayed Hassan Laser Application in Metrology, Photochemistry and Agriculture Dept., National Institute of Laser Enhanced Sciences (NILES), Cairo University
  • Ahmed Abddel Aziz Melegy Geological Sciences Dept., National Research Center (NRC), Giza, Egypt https://orcid.org/0000-0002-5207-3821
  • Ahmed Mohamed Abd-El kareem Soil Chemistry Dept. Desert Research Center (DRC), Cairo, Egypt
  • Manar Hassan Mohamed Laser Application in Metrology, Photochemistry and Agriculture Dept., National Institute of Laser Enhanced Sciences (NILES), Cairo University
Keywords: Egyptian synthetic zeolite-Y, Adsorption isotherms, Kinetic models, Cd2 , Removal, Distribution coefficient.

Abstract

Zeolite Na-Y was prepared from kaolin located in Wadi-Hagul, Suez, Egypt. The synthetic zeolite prepared by the hydrothermal reaction of kaolin was characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD), scanning electron microscopy (SEM) and cation exchange capacity (CEC). Cadmium ion removal was investigated using the synthetic solution of Cd2+ ions with different concentrations at room temperature (25 °C ± 0.2), initial pH of the solution and contact times. The optimum contact time for removal of Cd2+ ion was 10 min, with 0.1g of synthetic zeolite and pH 7.57. The experimental data were correlated using Langmuir, Freundlich and Harkins-Jura adsorption isotherms. The maximum adsorption capacity Qm obtained from the Langmuir isotherm was 14.006 mg/g for Cd2+ ion. Kinetic studies reveal that synthetic zeolite is more effective as adsorbent for removing cadmium ions

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Published
2020-05-17
How to Cite
Bahgaat, A., Hassan, H., Melegy, A., Abd-El kareem, A., & Mohamed, M. (2020). Removal of Cd2+ from aqueous solution by zeolite synthesized from Egyptian kaolin. Ukrainian Journal of Veterinary and Agricultural Sciences, 3(2), 12-23. https://doi.org/https://doi.org/10.32718/ujvas3-2.03